Operando Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Sodium–Oxygen Redox Reactions

Lower charge overpotential of sodium–oxygen (Na–O₂) batteries makes them a promising electrical storage technology. However, they have an undesirable discharge product, sodium carbonate (Na₂CO₃), which has widely been found in many previous studies. Whether and how the carbon components in the cathode are involved in the formation of Na₂CO₃ is still not well understood. Herein, an all solid-state Na–O₂ battery was constructed and its charge and discharge cycles were studied using ambient pressure X-ray photoelectron spectroscopy. The operando XPS results clearly demonstrate the formation of Na₂CO₃ on the cathode during the discharge cycle. A fraction of the carbonate formed can be cycled while charging the battery. Transformation of the carbon-based cathode to Na₂CO₃ is a potential cause of capacity fading of the Na–O₂ battery.     

Real-Time Path Planning Based on the Situation Space of UCAVs in a Dynamic Environment

This paper aims to find a reliable, collision-free path in a dynamic environment for highly maneuverable unmanned combat air vehicles (UCAVs). Given the real-time nature of the operational scenario, quick and adaptable reactions of UCAVs are necessary for updates in situational awareness. Therefore, we propose a three dimensional (3D) path planning approach based on the situational space to provide the tactical requirements of UCAVs for tracking targets and avoiding collisions. First, to ensure reliable nonlinear measurements, the interacting multiple model (IMM) algorithm based on a cubature Kalman filter (CKF) is chosen for the tracking and prediction algorithm. A constraint reference frame combining the kinematic model of constant acceleration (CA) is developed to solve the problem of arrival point generation. Second, by analyzing the relative motion between the UCAV and the moving objects, we define the situation space and give the corresponding calculation method. In tracking the moving target, the guidance vector contains the fusion information of displacement and velocity. At the same time, taking advantage of the one-step situation space as the judgment of the threat, we further plan the collision avoidance strategy. Third, as the safety in a practically reachable trajectory of the UCAV possesses the absolute priority, the collision avoidance acceleration accounts for this dominant factor in path planning. Simulations and experimental results prove that the proposed approach can plan a smooth and flyable path in 0.008 s under the premise of soft-landing target tracking.     

Cross-Layer Optimization of Dynamic Packet Assignment for Video Transmission Over IEEE 802.11e Networks

Video transmission over IEEE 802.11e wireless networks still shows poor performance for large bandwidth demand and frequently changed environments. Thus, several enhancements of IEEE 802.11e were proposed. On the other hand, big frames and simultaneous sending of adjacent frames always cause packet dropping for buffer overflow. In the past, we proposed an IEEE 802.11e enhancement named DFAA and a content aware mechanism to solve the above problems. The motivation of this paper is to find a proper way to integrate these two mechanisms. A DFAA enhancement (DFAA-E) is proposed to make up the insufficiency of content aware mechanism. Experiments results show that the combination of DFAA-E and content aware mechanism improves the video decoded quality greatly. And its performance can be further enhanced by selecting the suitable settings of certain parameters.     

Contrastive analysis of cooling performance between a high-level water collecting cooling tower and a typical cooling tower

A three-dimensional (3D) numerical model is established and validated for cooling performance optimization between a high-level water collecting natural draft wet cooling tower (HNDWCT) and a usual natural draft wet cooling tower (UNDWCT) under the actual operation condition at Wanzhou power plant, Chongqing, China. User defined functions (UDFs) of source terms are composed and loaded into the spray, fill and rain zones. Considering the conditions of impact on three kinds of corrugated fills (Double-oblique wave, Two-way wave and S wave) and four kinds of fill height (1.25 m, 1.5 m, 1.75 m and 2 m), numerical simulation of cooling performance are analysed. The results demonstrate that the S wave has the highest cooling efficiency in three fills for both towers, indicating that fill characteristics are crucial to cooling performance. Moreover, the cooling performance of the HNDWCT is far superior to that of the UNDWCT with fill height increases of 1.75 m and above, because the air mass flow rate in the fill zone of the HNDWCT improves more than that in the UNDWCT, as a result of the rain zone resistance declining sharply for the HNDWCT. In addition, the mass and heat transfer capacity of the HNDWCT is better in the tower centre zone than in the outer zone near the tower wall under a uniform fill layout. This behaviour is inverted for the UNDWCT, perhaps because the high-level collection devices play the role of flow guiding in the inner zone. Therefore, when non-uniform fill layout optimization is applied to the HNDWCT, the inner zone increases in height from 1.75 m to 2 m, the outer zone reduces in height from 1.75 m to 1.5 m, and the outlet water temperature declines approximately 0.4 K compared to that of the uniform layout.     

Finite Element Study on the Influence of Structural Parameters on the Ballistic Performance of 3D Networked Fabrics

Networked fabrics are a type of three-dimensional multilayer fabrics having predetermined interconnections between layers by combining yarns from two adjacent sublayers into one. This paper reports the research on the influence of structural parameters on the ballistic performance of networked fabrics using finite element analysis in parallel with experiment. The widths of separate and combined sections are found to affect the energy absorption (EA) of regular networked fabrics against high-velocity impact. Separate sections of networked fabrics generally outperform combined sections. The optimal width of the separate section is around 9.5 cm for both dense and loose networked fabrics when impacted at the separate section. The optimal width of combined section decreases from 2.38 cm to 1.15 cm with the decrease of weave density in this area. For the studied structural parameters, highest EAs of dense and loose networked fabrics are around 13.3% and 17.1% higher than those of their counterpart layups of dense and loose plain-woven fabrics, respectively. These findings suggest networked fabrics could be engineered to improve the ballistic performance of flexible fabrics.     

Improving the physical and mechanical properties of particleboards made from urea–glyoxal resin by addition of pMDI

The effect of pMDI on physical and mechanical properties of the particleboards made from urea–glyoxal resin was investigated. The nontoxic and ecofriendly urea–glyoxal (UG) resin was synthesized under weak acid conditions, and its different properties were measured. Then, pMDI at various contents (4, 6 and 8% on resin solids) was added to the UG resin prepared. The thermal and physicochemical properties of the resins prepared as well as their water absorption, flexural properties (flexural modulus and strength) and internal bond (IB) strength of the particleboard panels bonded with them were measured according to standard methods. According to the physicochemical results obtained, the addition of pMDI significantly accelerated the gel time and increased the viscosity and solids content of UG resins. Differential scanning calorimetry indicated that the addition of pMDI decreases the onset and curing temperatures of the UG resin. Physical analysis results of the panels indicated that the particleboards made from UG resins with isocyanate yielded lower water absorption when compared to those bonded with the control UG resins. Based on the findings of this research work, the mechanical properties of particleboard panels bonded with UG resins could be significantly enhanced by the addition of increasing percentages of pMDI. The panels having 8 wt% pMDI exhibited the highest flexural modulus, flexural strength and IB strength value and the lowest water absorption among all the panels prepared.     

Optimal sensor placement for joint parameter and state estimation problems in large-scale dynamical systems with applications to thermo-mechanics

We consider large-scale dynamical systems in which both the initial state and some parameters are unknown. These unknown quantities must be estimated from partial state observations over a time window. A data assimilation framework is applied for this purpose. Specifically, we focus on large-scale linear systems with multiplicative parameter-state coupling as they arise in the discretization of parametric linear time-dependent partial differential equations. Another feature of our work is the presence of a quantity of interest different from the unknown parameters, which is to be estimated based on the available data. In this setting, we employ a simplicial decomposition algorithm for an optimal sensor placement and set forth formulae for the efficient evaluation of all required quantities. As a guiding example, we consider a thermo-mechanical PDE system with the temperature constituting the system state and the induced displacement at a certain reference point as the quantity of interest.     

A comparison study of Taiwanese He-Yuan Architecture between the ethically spatial order and the condition of physical environment

Since the 21st century, problems such as global warming and energy depletion have become important issues to scientists and architects. The architectural design nowadays often relies on large amount of mechanical equipment to create a comfortable environment for the users. However, it burdens and deteriorates the nature. On the other hand, some of the traditional architecture in the past can cope with the local humid and hot climate, achieving good passive heat control for the environment. Therefore, this study explores the relation between traditional residents in Taiwan’s use of space and the external environment and climate through modern environment measurement technique, restores and conducts quantitative analysis on the interior thermal environment and light environment of Lin-An-Tai Historical House in the past through Ecotect Analysis, and analyzes the results of the calculation in terms of its spatial allocation, openings, and outer walls, etc. This study also evaluates the effects of lighting and user’s sense of comfortable temperature under its environmental conditions according to the standards of residential quality nowadays. It further studies the ancestor of traditional architecture by reviewing its spatial order and compares to the current situation in order to feedback the modern architecture design. Part of the results of the simulation show that the variation of temperature indoors in each space is less dynamic than that of outdoors. The temperature in the space at the right of the main hall (northwestern side) is generally higher than that in the left (southeastern side). The highest temperature in the space farther away from the interior patio is usually higher than that in the space closer to the interior patio. The temperature near the outer side of the space above Hulong is higher than that in the middle. Accordingly, the location is closely related to the interior temperature. As to human’s sense of comfortable temperature, the results show that in summer, the Predicted Mean Vote (PMV) in the space at the left of the main hall (southeastern side) is generally higher than that in the right (northwestern side). In winter, the sense of comfortable temperature in the rooms in the corner is lower than that in other rooms at the inner side, the comparison between the space ethical order and the evaluation result did not show any obvious relationship. For the evaluation of lighting, the main hall and the restaurant at the outer left Hulong have better lighting while other space does not have sufficient and even lighting. Artificial lighting is needed to make the space more functional, the results shows that lighting conditions of space did not metaphor to the space ethical order.     

An experimental investigation on slope stability under drawdown conditions using transparent soils

This paper presents an experimental investigation into slope failure during water-level drawdown using transparent soil. The internal characteristics of slope failure are not well-known due to the limitations of the techniques used in the experiments conducted to date. In this study, transparent soil is used to visualize the process of slope failure. We developed a water-level control system to implement simulation of the drawdown of the water level at various speeds and used a charge-coupled device camera to capture images during the entire slope failure process. Particle image velocimetry was used to measure the displacement of the sand particles and identify the sliding zones. The flow paths of the fluid inside the slope were illuminated using an organic dye. The results show that the slope failure process can be divided into two stages: surface and overall sliding. The overall sliding of the slope is caused by the gradual development of partial instability, and the failure mode is a cyclic failure. The slope angle is different above and below the water level during the process of sliding. In our experiments, the slope angle is about 20° above the water level, which is the same as the final stable slope angle, and about 35° below the water level, which is the same as the initial slope angle. This means that the drawdown influences the angle above the water level but has little influence on the angle below the water level. The results of this paper provide a better understanding of the physical behavior and failure mode of soil slopes caused by drawdowns near the coast.